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You have to use the same method you use when identifying the main character in an RPG: Whoever has the craziest hairstyle. Redneck is clearly not the leader, as his hairstyle is merely a lamer version of Christmas Boy's, although even his hairstyle pales in comparison to that of goggles head. Perhaps his goggles are a symbol of power, sort of like a crown.
Normally that would work, but emo has it's own subculture (or anti-culture) where all the rules aren't the same. It obviously can't be Redneck Boy because his belt bucket makes reference to a different subculture. That would be cross contamination. Christmas boy is forced to have a similar haircut to show his lack of Alpha-dominance in the group. It's possible that Ghost Pale Chick could be the leader, what with making Goggle Head (the new guy) wear pink pantyhose to show her dominance over the group, but she's obviously just a groupy here which is why she has a little bit of something similar with every other member of The Emo Kids. That leaves Corduroy Boy (assuming those pants 
