Vincent has the lowest statgrowths in the game, Yuffie and Barret make him obselete.
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Aeris
The Luck plus materia you find after following the second ancient spirit?
Nope.
Damn that was gonna be my next guess... Work Glove?
Is it the Purple guy you have to chase down? I believe he's a Ancient...
Is it one of the dead end rooms in the Temple of Ancient's Clock Room?
If not, does the riddle even talk about the Temple of Ancients, or is that a little trick?
It is a reference to the temple of the Ancients, right?
Edit: I swear I didn't see the above post.
temple may refer to where it is supposed to be used. As in a gun.
That case, I would guess the Highblow ST
[note, Highbrow (or possibly High Blow) weapon does exist in the game but was mistranslated and instead called Supershot ST. ハイブロウST > Haiburou ST > Highbrow ST EUdict | ハイブラウ | Japanese (Kanji)-English dictionary ]
Cid's goggles?