When I first ventured into chat, it was 2005 and I was just some dumb kid. I did however meet some awesome people and many of them became good friends (who all subsequently left EoFF forever and now do real life things on Facebook). I was never intimidated by the thought of chat, but I can see why people would be, particularly if it's a busy period. I think it's a great subset of the EoFF community, and it would be excellent to see some new (or would it be old?) faces coming in from time to time.
If you want to see if chat is your thing, just have a go. What is the worst that could happen?