I have two great events, both from Pro Evo 3, and both from England v France.

The first was a five-star difficulty Euro 2004 clone. It was England v France, and I played the 5-4-1 formation that Tony Adams said England should use. England won 6-1, Michael Owen scoring all 6 xD

The other was in a four-star World Cup. England v France - The Final! It was 2-1 to France, and the game was in the 89th minute. Rooney went on a mazey run (I changed the stats of a lot of players to make them better/worse ) and drilled the ball hard and low into the bottom corner. I was thrilled. Then, during Injury time, Beckham runs down the right wing, hooks over a cross, and Michael Owen heads the ball right past Barthez. 3-2. Bliss.