Vanille doesn't have the extra accessory ability in her crystarium yet. Sazh does, but not Vanille. I have both of their crystariums maxed out.
edit: so previously I was going after Enki first (the lighting-weak one). I switched to going after Enlil first (the water-weak one) and succeeded on my first try. I didn't do anything else different, except maybe keeping Vanille on Medic more often. Go figure.
edit 2: Accessory shows up in Vanille's crystarium after you win the battle.






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