Without knowing the effects on the planet? They may not have known about the affects of detonating the huge materia, but they had a fairly good idea about the affects of Meteor. And anything is up from there.
And the fact that it blew half of meteor apart without the full payload is a definite reason to have tried it at full strength. Though the FMV is the same regardless, so we never get to know the true strength of the weapon.

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