I really like the scenes with the Mayor of Fisherman's Horizon, there's some interesting stuff there that is touched upon but overshadowed by the reunion scene that immediately follows, and the light relief Irvine stuff after that.

The Zidane and Vivi pissing scene is really nice and sweet and placed about right where it needs to be.

Zidane meeting Freya in the pub is a good one too now that I think of FF9 - overshadowed by the fact they do smurf all with Freya after her little arc.